With all of them looking gorgeous, it was opera singer Katherine Jenkins who was the highlight of the evening, stealing the limelight in a revealing dress that accentuated her huge bust.
Other celebs who joined her on the catwalk were Cheryl Cole, Jamelia, Daisy Lowe, The Sugababes, Roisin Murphy plus rock star daughters Lizzie Jagger, Jade Parfitt and Kimberly Stewart, as well Naomi herself.
The ladies all helped in making the event one of London Fashion Week's most glamorous nights so far.
Cilla Black also made a rather embarrassing appearance on the catwalk, recreating her shameless display at the 2001 Royal Variety Performance - although it was all in good fun.
Model Tyson Beckford flexed his pecs on the catwalk right in front of the PM's wife Sarah Brown, who, understandably, gave him an admiring glance.