Pablo Picasso's colorful "The Women of Algiers (Version 0)," depicting a scene from a harem, will be up for grabs when Christie's puts it on the auction block May 11.
The same goes for Alberto Giacometti's bronze statue "Man Pointing," of which there are only six casts in the world.
The painting and statue are the flagship works at the evening sale entitled "Looking Forward to the Past," which will see 35 pieces of art created between 1902 and 2011 auctioned off.
The rising price of artwork at auctions is attributed to a growing number of wealthy, private investors around the world, experts say.
Giacometti's nearly six-foot (1.8-meter) depiction of a wiry man holding up one hand and pointing with the other is the artist's "most celebrated sculpture," Gouzer said.
The Swiss sculptor's masterpiece represents "when Giacometti became Giacometti, the ultimate work, the Holy Grail of sculpture."
Meanwhile, Picasso's nearly four-by-five-foot canvas is "a masterpiece at the level of 'Guernica' and 'Les Demoiselles d'Avignon,'" Gouzer said.
"He painted several versions until he got this one," he added.
Picasso created the painting in 1955, inspired by 19th-century French painter Eugene Delacroix, but as a homage to Henri Matisse, who died in November 1954.
The work is one of the last major paintings by the Spanish master in private collection.
The world record for a painting sold at auction is $142.4 million for Francis Bacon's "Three Studies of Lucian Freud," which was snapped up in New York in 2013.
And the record for priciest sculpture is already held by Giacometti, whose "Walking Man I" sold for $104.3 million in London in 2010.
- 'Among biggest sales ever' -
Also up for grabs to the highest bidder will be a painting from Claude Monet's "The House of Parliament" series, expected to bring in between $35 million and $45 million, and Mark Rothko's 1958 "No 36, Black Stripe," with an estimated value of $30-$50 million.
New York's eagerly anticipated spring auction season begins on Tuesday, when Sotheby's presents 69 impressionist and modernist works worth an estimated total value of more than $270 million.
Among them are six Monets, all from private collections, with an estimated value of $110 million, including a "Water Lilies" painting valued at between $30 million and $45 million.
Another star of the evening will be Vincent Van Gogh's 1888 "Les Alyscamps," created during his time in Arles, France and worth more than $40 million.
At a Sotheby's auction of contemporary art on May 12, works worth about $320 million will be sold in 65 lots, to include works by Rothko, Roy Lichtenstein and Gerhard Richter.
Michael Macaulay, a contemporary art specialist for Sotheby's, called the auction "one of our biggest sales ever."
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