A particle that could "cool the planet" and naturally clean up the atmosphere has been discovered by scientists.
According to researchers from The University of Manchester, The University of Bristol and Sandia National Laboratories, Criegee biradicals are invisible chemical intermediates and are powerful oxidisers of pollutants such as nitrogen dioxide and sulfur dioxide, produced by combustion.
AdvertisementAlthough these chemical intermediates were hypothesised in the 1950s, it is only now that they have been detected. Scientists now believe that, with further research, these species could play a major role in off-setting climate change.
The detection of the Criegee biradical and measurement of how fast it reacts was made possible by a unique apparatus, designed by Sandia researchers, that uses light from a third-generation synchrotron facility, at the Lawrence Berkeley National Laboratory's Advanced Light Source.
The intense, tunable light from the synchrotron allowed researchers to discern the formation and removal of different isomeric species - molecules that contain the same atoms but arranged in different combinations.
The researchers found that the Criegee biradicals react more rapidly than first thought and will accelerate the formation of sulphate and nitrate in the atmosphere. These compounds will lead to aerosol formation and ultimately to cloud formation with the potential to cool the planet.
Carl Percival, Reader in Atmospheric Chemistry at The University of Manchester and one of the authors of the paper, believes there could be significant research possibilities arising from the discovery of the Criegee biradicals.
"Criegee radicals have been impossible to measure until this work carried out at the Advanced Light Source. We have been able to quantify how fast Criegee radicals react for the first time," Percival said.
"Our results will have a significant impact on our understanding of the oxidising capacity of the atmosphere and have wide ranging implications for pollution and climate change.
"The main source of these Criegee biradicals does not depend on sunlight and so these processes take place throughout the day and night," he added.
The study has been published in Science.
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